Refer to special instructionsmaterial safety data sheets. Section 11 toxicological information information on toxicological effects acute effects. From 1% to 100% dlimonene formulations, in air fresheners to drain cleaners to industrial degreasers, all products use the highestquality dlimonene and are designed for the highest performance. Label elements signal word danger hazard statements h226 flammable liquid and vapor h315 causes skin irritation h317 may cause an allergic skin reaction h410 very toxic to aquatic life with long lasting effects h304 may be fatal if swallowed and enters airways precautionary statements. Uses advised against food, drug, pesticide or biocidal product use.
The most complete free material safety data sheet msds list of chemical information on the internet chemical information material safety data sheets msds msdss direct from the manufacturers websites. As with any chemical, employees should thoroughly wash hands with soap and water after handling this material. D limonene is a highly refined solvent, with a strong pleasant citrus odour. It is safe for consumers and other users under normal and reasonably foreseeable use. Firstaid measures general advice if symptoms persist, call a physician. It is also used in chemical synthesis as a precursor to carvone and as a renewablesbased solvent in cleaning products. Methods and material for containment and cleaning up methods for cleaning up. Combustible material that has been soaked with d limonene may spontaneously combust. Safety data sheet northwest missouri state university.
With dry hydrogen chloride or hydrogen bromide, it forms monohalides. Removes grease, oil, tar, carbon deposits, cutting fluids, food soils, blood, ink, paint, and adhesives, from. Safety data sheet quik fill 86 dlimonene degreaser 91726008 4 11 listed in sections 7 and 8. Arco dlimonene cleaner msds download sevron safety.
First aid measures general advice consult a physician. Safety data sheet according to federal register vol. Identification of the substancemixture and of the companyundertaking. Technical grade d limonene productdata preparation date. Enjoy the relaxing and rejuvenating aroma of pure citrus as you use dlimonene to clean your home. The oxidized forms of dlimonene have been shown to be skin sensitizers. It is biodegradable, nontoxic and considerably less harmful to humans than traditional solvents. This product has been classified in accordance with the hazard criteria of the cpr and the msds contains all the. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.
Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Find msds limonene related suppliers, manufacturers, products and specifications on globalspec a trusted source of msds limonene information. People already sensitized to turpentine or terpenes may also be allergic to d limonene. Chemical stability autoxidation facilitated by light and air.
The major metabolite associated with alpha2uglobulin was d limonene 1,2oxide. Dietary supplements of d limonene are typically produced from the peels of oranges, with a typical dose of 1,000 mg per capsule. Whether youre cleaning your stone countertops or removing laundry stains, youll get to enjoy a pleasant citrus scent, not a harsh chemical smell. On irradiation, it undergoes radiolysis, which leads to a reduction in the optical purity.
S limonene also shows potent antimicrobial activity. This product is intended for consumer use and is labeled according to cpsc guidelines and not to ghs guidelines listed below. In its pure form, d limonene is not a sensitizer, but its oxidized form is a known skin sensitizer. The most important known symptoms and effects are described in the labelling see section 2 andor in section 11. The d isomer, occurring more commonly in nature as the fragrance of oranges, is a flavoring agent in food manufacturing. A person consuming 1 2 servings of citrus per day is likely to get 15 40 mg of d limonene. Carcinogenicity risk of cancer based on available data, the classification criteria are not. Product identifier and chemical identity product identifier d limonene other names dipentene manufacturers product code 16888.
S limonene, a monoterpenoid compound, is mostly used in perfumery and in flavoring. Show this safety data sheet to the doctor in attendance. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. With aqueous hydrogen chloride or hydrogen bromide, it forms the. Using reverse phase hplc, d limonene was shown to be associated with alpha2uglobulin which was identified by amino acid sequencing. Msdsonline ondemand msds chemical management and injury and illness compliance solutions. This substance does meet the criteria for classification as dangerous in accordance with. There was no evidence of carcinogenic activity of d limonene for female rats, for male mice, or for female mice.
If you feel unwell, seek medical advice show label where possible. Arco d limonene cleaner safety data sheet download 344900525 msds ghs clp. Never give anything by mouth to an onconscious person. Product may be packaged in phenoliclined steel containers or fluorinated plastic containers.
For use on containers that store limonene to ensure the workplace is aware of the immediate chemical hazards that are present. Acute and subchronic nephrotoxicity of d limonene in fischer 344 rats. Acgih no component of this product present at levels greater than or equal to 0. May cause an allergic skin reaction in susceptible individuals. Show a copy of this msds to medical personnel dealing with cases of over exposure. Material safety data sheet d limonene form 21047, revision 3, page 4 of 8, document 6225125, 18 mar 2015 11. Oxides of d limonene, which can result from improper storage and handling, are known to cause skin sensitization. Harmonized system of classification and labeling of chemicals ghs. Ghs globally harmonized system of classification and labelling of chemicals hsno hazardous substances and new organisms. In 2year gavage studies, there was clear evidence of carcinogenic activity of d limonene for male rats, as shown by increased incidences of tubular cell hyperplasia, adenomas, and adenocarcinomas of the kidney. Citrus clean safety data sheet according to federal register col.
Parent d limonene was also identified as a minor component in the alpha2uglobulin fraction. Atheas expertise in dlimonene products is unmatched in the industry. Globally harmonized system no data available specific target organ toxicity repeated exposure globally harmonized system. Nfpa rating extinguishing media flammable limits none not. This chemical is incompatible with strong oxidizing agents.
Material safety data sheet limonene april 11, 2005 identity as used on label and list page 2 of 2 section 4 fire fighting measures carbon dioxide, water, water fog, dry chemical, chemical foam. Redox pty ltd safety data sheet dlimonene revision 2. Arco dlimonene cleaner safety data sheet download 344900525 msds ghs clp. D limonene terpene hydrocarbons no data available 68647723 93. Redox pty ltd safety data sheet dlimonene revision 2, date. Review of kidney sections from a subchronic d limonene oral dosing study conducted by the national cancer institute. Not classified as flammable, but will burn if heated or exposed to a flame. See section 16 for full text of ghs classification and h phrases 4. Get your ghscompliant labels and signs from safety emporium. Finally, there is no evidence that any human protein can contribute to a renal syndrome similar to. Specific hazards arising from the chemical during fire, gases hazardous to health may be formed including oxides of carbon, nitrogen, and. A person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical. All whmis required information is included in appropriate sections based on the ansi z400.
Identification of the substancemixture and of the companyundertaking 1. Compliant with the osha hazard communication standard 1910. Dlimonene citrus terpenes, cas 94266474 ghs chemical container label dependable 3m adhesive vinyl that is built to resist harsh conditions. If inhaled if breathed in, move person into fresh air.
Safety data sheet d limonene technical grade container. Safety evaluation and risk assessment of dlimonene, toxicol environ. Ghs label elements, including precautionary statements. Do not allow contact with soil, surface or ground water. The most complete free material safety data sheet msds. Msds software is used to create, manage and distribute material safety data sheets msds for chemical products. Find msds or sds, a coa, data sheets and more information. Product name champions choice d limonene degreaser chemical name 781091 other means of identification product code fg 43853505 synonyms degreaser recommended use of the chemical and restrictions on use recommended use removes grease, tar, oil, grime, adhesives, stickers, gum, printers ink, wet paint, most graffiti, and other oilbased. Powerful natural dlimonene based cleanerdegreaser is ideal for removing the toughest soils from metals, concrete, floors, equipment, tools, and other hard surfaces. Safety data sheet section 1 chemical product and company. Ghs safety data sheet trisolv hazard statements precautionary statements health environmental physical. Durable laminate that increases the label strength and resistance.
Comparison of shortterm renal effects due to oral administration of decalin or d limonene in young adult male fischer344 rats. Carcinogenicity risk of cancer based on available data, the classification criteria are not met. Solvent mixture containing detergent, used to degrease. Arco dlimonene cleaner msds download sevron safety software.
Technical grade d limonene technical grade d limonene 160358. Manage material safety data sheets sds with msdsonline. Update to ghs sds standard this msds summarises product safety information at the date of issue, to the best of our knowledge, as a general guide. Este producto no esta clasificado como carcinogeno por osha, iarc, acgih o ntp. Relevant identified uses of the substance or mixture and uses advised against use of substance mixture.
D limonene is a type of terpene called a monoterpene. For use on containers that store dlimonene to ensure the workplace is aware of the immediate chemical hazards that are present. Material safety data sheet deep south chemical, inc. L limonene 5989548 80 100 pcymene 99876 1 4 d limonene 5989275 1 4 1,8cineol 470826 1 4 4.
Tested to withstand exposure to acetone, dichloromethane, hydrofluoric acid, and other tough chemicals and solvents. A clean and bright fluid which leaves a lasting citrus orange odour. D limonene is regularly used in the manufacture of cleaning chemicals, paints and surface coatings, cosmetics, perfumes and pharmaceuticals. Limonene is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the oil of citrus fruit peels. Carroll company now carroll clean dg90 natural citrus. Causes skin irritation with redness, itching and discomfort. See section 16 for full text of ghs and eu classifications.
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